当前位置: X-MOL 学术CrystEngComm › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Phase transitions and photoluminescence switching in hybrid antimony(III) and bismuth(III) halides
CrystEngComm ( IF 3.1 ) Pub Date : 2020-03-31 , DOI: 10.1039/d0ce00057d
Nannan Shen 1, 2, 3, 4, 5 , Zeping Wang 1, 2, 3, 4, 5 , Jiance Jin 1, 2, 3, 4, 5 , Liaokuo Gong 1, 2, 3, 4, 5 , Zhizhuan Zhang 1, 2, 3, 4, 5 , Xiaoying Huang 1, 2, 3, 4, 5
Affiliation  

Main group metal ions antimony(III) and bismuth(III) with external electron shell of s2 configuration belong to the so-called mercury-like ions. Recently, luminescent antimony(III) and bismuth(III) hybrid halide compounds have aroused great research interest. In particular, the aggregation/crystallization induced emission in hybrid antimony(III) and bismuth(III) halides endows them with molecular packing dependent emissive properties. As a result, they exhibit great potential for achieving reversible phase transformations and switchable photoluminescence (PL) under external stimuli. In this review article, recent advances in this context are highlighted with the aid of illustrative examples, and the structure–optical property relationships are further emphasized. The present challenges and future prospects of smart hybrid antimony(III) and bismuth(III) halides are also demonstrated.

中文翻译:

混合锑(III)和卤化铋(III)的相变和光致发光转换

具有外部电子壳为s 2构型的主族金属离子锑(III)和铋(III)属于所谓的汞状离子。近来,发光锑(III)和铋(III)杂化卤化物引起了极大的研究兴趣。特别是,在混合锑聚集/结晶诱导发光(III)和铋(III)卤化物使它们具有依赖分子堆积的发射特性。结果,它们显示出在外部刺激下实现可逆相变和可切换光致发光(PL)的巨大潜力。在这篇综述文章中,借助示例性实例强调了在此背景下的最新进展,并进一步强调了结构-光学性质的关系。还展示了智能混合锑(III)和卤化铋(III)的当前挑战和未来前景。
更新日期:2020-03-31
down
wechat
bug