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[Ag(PcL)]‐Catalyzed Domino Reactions of 2‐Alkynylbenzaldehydes with Electron‐Poor Anilines: Synthesis of 1‐Aminoisochromenes
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-04-15 , DOI: 10.1002/ejoc.202000275
Valentina Pirovano 1 , Gabriele Hamdan 1 , Davide Garanzini 1 , Elisa Brambilla 1 , Elisabetta Rossi 1 , Alessandro Caselli 2 , Giorgio Abbiati 1
Affiliation  

A series of neglected 1‐aminoisochromenes have been prepared under mild condition by a selective domino reaction between 2‐alkynylbenzaldehydes and electron‐poor anilines catalyzed by original silver(I) complexes characterized by the presence of a pyridine containing macrocyclic ligand [AgIPcL].
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中文翻译:

[Ag(PcL)] 2-炔基苯甲醛与电子贫苯胺的多米诺反应催化:1-氨基异色酮的合成

在温和的条件下,通过以原始的银(I)配合物为特征的2-炔基苯甲醛与贫电子苯胺之间的选择性多米诺反应,制备了一系列被忽略的1-氨基异色酮,其特征在于存在含吡啶环的大环配体[Ag I PcL] 。
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更新日期:2020-04-15
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