Ni/SiO₂ and SiO₂-supported Ni₃Ga and Ni₅Ga₃ intermetallic compounds were prepared by the sol-gel method and evaluated for the hydrodeoxygenation of various phenolic compounds at 0.1 MPa. In the hydrodeoxygenation of anisole, Ni₃Ga/SiO₂ was more active for direct deoxygenation to benzene than the corresponding catalyst prepared by the impregnation method as well as Ni/SiO₂. The anisole conversion and selectivity to benzene reached 95.1% and 92.5% on Ni₃Ga/SiO₂ at 300 °C and WHSV of 2 h⁻¹, respectively. In the HDOs of cresols and guaiacol, Ni₃Ga/SiO₂ still more dominatingly facilitated the direct deoxygenation, while Ni/SiO₂ significantly promoted the C-CH₃ bond cleavage.

通过溶胶-凝胶法制备Ni / SiO ₂和SiO ₂负载的Ni ₃ Ga和Ni ₅ Ga ₃金属间化合物，并在0.1MPa下评价各种酚类化合物的加氢脱氧。在苯甲醚的加氢脱氧中，Ni ₃ Ga / SiO ₂与通过浸渍法制备的相应催化剂以及Ni / SiO ₂相比，对于直接脱氧成苯更具活性。在300°C和2 h ^-1的WHSV下，Ni ₃ Ga / SiO ₂上的苯甲醚转化率和对苯的选择性分别达到95.1％和92.5％。在甲酚和愈创木酚的HDO中，Ni ₃Ga / SiO ₂仍然更直接地促进直接脱氧，而Ni / SiO ₂显着促进C-CH ₃键的裂解。