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Intensified pharmaceutical and personal care products removal in an electrolysis-integrated tidal flow constructed wetland
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2020-03-28 , DOI: 10.1016/j.cej.2020.124860
Xianjing Liu , Cunzhen Liang , Xiaohui Liu , Shaoyong Lu , Beidou Xi

To improve the removal of pharmaceutical and personal care products (PPCPs) from contaminated water, a novel electrolysis-integrated tidal flow constructed wetland system (E-TFCW) was developed. E-TFCWs have the highest removal efficiency for the four investigated PPCPs when the electrodes are arranged at the bottom of the E-TFCWs. The removal efficiency of four PPCPs increases from 4.41%-11.71% to 28.83%-68.32% when using electrolysis combined with tidal flow constructed wetlands. The synergy effect for the degradation of PPCPs between electrolysis and constructed wetlands on the degradation of PPCPs in E-TFCWs were significant (enhancement factor >1), while the removal efficiency of PPCPs after the electrolysis (10 h, accounting for 14.98%-44.41%) is higher than that before electrolysis (10 h, accounting for 9.62%-27.14%) and electrolysis process (4 h) accounting for 42.81%-68.47%. Electrolysis can enhance the removal of PPCPs through direct oxidation. Moreover, the increase in intermediate oxidation compounds in the E-TFCWs may imply the enhanced biodegradability of PPCPs during the electrolysis process since the by-products of PPCPs were identified. The contents of Thermomonas, Microbacterium, Cloacibacterium and Acidovorax at the bottom of the E-TFCWs were significantly higher than those of other bacteria, which contributed to the removal of PPCPs. Electrolysis can enhance the biodegradability of PPCPs and the formation of anoxic/aerobic conditions for the growth of predominant bacteria, which contributes to the degradation of PPCPs in the E-TFCWs. The results illustrate that electrolysis-integrated tidal flow constructed wetlands are an effective technology for the removal of PPCPs.



中文翻译:

在电解整合的潮汐人工湿地中加强药物和个人护理产品的去除

为了改善从污水中去除药品和个人护理产品(PPCP)的能力,开发了一种新型的电解集成潮汐人工湿地系统(E-TFCW)。当电极布置在E-TFCW的底部时,对于四个被调查的PPCP,E-TFCW的去除效率最高。当使用电解结合潮汐人工湿地时,四种PPCP的去除效率从4.41%-11.71%提高到28.83%-68.32%。电解和人工湿地之间PPCP降解的协同效应对E-TFCWs中PPCP的降解具有显着影响(增强因子> 1),而电解后PPCP的去除效率(10 h,占14.98%-44.41)。 %)高于电解前(10 h,占9.62%-27)。14%)和电解过程(4 h)占42.81%-68.47%。电解可以通过直接氧化来增强PPCP的去除。此外,E-TFCWs中的中间氧化化合物的增加可能暗示着在电解过程中PPCPs的生物降解性增强,因为已识别出PPCPs的副产物。内容E-TFCWs底部的热单胞细菌梭菌嗜酸杆菌显着高于其他细菌,这有助于去除PPCP。电解可以增强PPCPs的生物降解能力,并形成主要细菌生长的缺氧/好氧条件,这有助于E-TFCWs中PPCPs的降解。结果表明,电解整合的潮汐人工湿地是去除PPCPs的有效技术。

更新日期:2020-03-28
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