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Acridine orange as a coreactant for efficient electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) and its use in selective and sensitive detection of thiourea.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-04-07 , DOI: 10.1039/d0cc01273d
Muhammad Saqib 1 , Shahida Bashir , Shimeles Addisu Kitte , Haijuan Li , Yongdong Jin
Affiliation  

A new and efficient anodic Ru(bpy)32+ ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in a neutral medium. The developed Ru(bpy)32+-AO system displayed a higher ECL intensity than that of the classic Ru(bpy)32+- oxalate ECL system, and was further exploited for the ECL detection of thiourea for the first time.

中文翻译:

cr啶橙作为三(2,2'-联吡啶)钌(ii)高效化学发光的共反应剂,可用于硫脲的选择性和灵敏检测。

据报道,在中性介质中,通过使用orange啶橙(3,6-双(二甲基氨基)ac啶,AO)作为共反应剂,新型高效的Ru(bpy)32+ ECL阳极系统。已开发的Ru(bpy)32 + -AO系统显示出比传统Ru(bpy)32 +-草酸盐ECL系统更高的ECL强度,并首次被进一步用于硫脲的ECL检测。
更新日期:2020-03-27
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