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Synthesis, characterization and photoluminescent properties of Sm 3+ /Dy 3+ doped strontium zirconate perovskites
Journal of Electroceramics ( IF 1.7 ) Pub Date : 2020-03-26 , DOI: 10.1007/s10832-020-00207-6
Meenu Venugopal , H. Padma Kumar , R. Jayakrishnan

Photoluminescent properties of Sm3+/ Dy3+ single and co-doped SrZrO3 perovskites, prepared through conventional solid state ceramic route method were investigated. X-ray diffraction studies confirmed the orthorhombic (Pnma) perovskite structure of the calcined samples. Dy3+doped SrZrO3 systems showed blue emission at 482 nm and yellow emission at 574 nm due to the transition between 4F9/2-6H15/2 and 4F9/2-6H13/2 levels respectively while Sm3+ doped SrZrO3 systems shows red emissions at around 567 nm, 603 and 646 nm that respectively corresponds to the 4G5/2 → 6H5/2, 4G5/2 → 6H7/2 and 4G5/2 → 6H9/2 transitions of Sm3+. Sm3+/ Dy3+ co-doped SrZrO3 systems shows two different emissions for excitations at 350 nm and 407 nm. Near white light emission was achieved for the SrZr0.9Sm0.025Dy0.075O3, SrZr0.9Sm0.05Dy0.05O3 andSrZr0.9Sm0.075Dy0.025O3 systems at 354 nm excitation with CIE colour co-ordinates (0.3792, 0.3849), (0.3813, 0.3853) and (0.3786, 0.3851) respectively.



中文翻译:

Sm 3+ / Dy 3+掺杂锆钛酸锶钙钛矿的合成,表征和光致发光性能

研究了通过常规固态陶瓷路线法制备的Sm 3+ / Dy 3+单和共掺杂SrZrO 3钙钛矿的光致发光性能。X射线衍射研究证实了煅烧样品的正交晶(Pnma)钙钛矿结构。的Dy 3+掺杂SrZrO 3个系统由于过渡显示出在574处纳米482纳米和黄色发射的蓝色发射之间4 ˚F 9/2 - 6 ħ 15/24 ˚F 9/2 - 6 ħ 13/2分别水平,同时Sm 3+掺杂的SrZrO 3系统示出了在约567纳米,红色发射603和分别对应于646纳米的4 ģ 5 / 2  →  6 ħ 5 / 24 ģ 5 / 2  →  6 ħ 7 / 24 ģ 5 / 2  →  6 ħ 9 / 2跃迁的Sm 3+。Sm 3+ / Dy 3+共掺杂SrZrO 3系统显示了在350 nm和407 nm处激发的两种不同发射。SrZr 0.9 Sm 0.025 Dy 0.075 O 3,SrZr 0.9 Sm 0.05 Dy 0.05 O 3和SrZr 0.9 Sm 0.075 Dy 0.025 O 3系统在354 nm激发下以CIE颜色坐标(0.3792,0.3849)实现了近白光发射, (0.3813,0.3853)和(0.3786,0.3851)。

更新日期:2020-04-21
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