Synthesis of Polybenzoacenes: Annulative Dimerization of Phenylene Triflate by Twofold C−H Activation,Angewandte Chemie International Edition

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Synthesis of Polybenzoacenes: Annulative Dimerization of Phenylene Triflate by Twofold C−H Activation
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2020-03-25 , DOI: 10.1002/anie.202003863
Mizuho Uryu ₁ , Taito Hiraga ₁ , Yoshito Koga ₁ , Yutaro Saito ₁ , Kei Murakami _{1,

2} , Kenichiro Itami _{1,

2,

3}

Affiliation

Polycyclic aromatic hydrocarbons (PAHs) are an emerging class of aromatic molecules in materials science. In their Research Article (DOI: 10.1002/anie.202001211), K. Itami, K. Murakami, et al. present the development of a palladium‐catalyzed annulative dimerization of phenylene triflate by twofold inter‐ and intramolecular C−H activation. This transformation forms two C−C bonds in one go, which enables the rapid synthesis of a variety of PAHs.

中文翻译：

聚苯并二乙炔的合成：三氟甲烷的双重CHH活化环化二氟苯磺酸

多环芳烃（PAH）是材料科学中新兴的一类芳族分子。在他们的研究文章（DOI：10.1002 / anie.202001211）中，K。Itami，K。Murakami等人。目前通过三价分子间和分子内CH活化激活了三氟甲磺酸苯催化钯环化二聚。这种转变可以一口气形成两个C-C键，从而可以快速合成多种PAH。

更新日期：2020-03-26

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