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Corrosion behaviour of Al-containing high Cr ferritic oxide dispersion strengthened steel in nitric acid environment
Journal of Nuclear Materials ( IF 3.1 ) Pub Date : 2020-03-23 , DOI: 10.1016/j.jnucmat.2020.152120
R. Priya , S. Ningshen , M. Sakairi , S. Ukai

Higher chromium containing 17Cr oxide dispersion strengthened (ODS) steel (Fe-16.78Cr-4.46Al-0.5Ti-0.45Y2O3-0.36Y) with the ferritic structure are a prospective applicant fuel cladding materials for the high operating temperatures of future advanced nuclear reactors system. In this study, the microstructure, passive oxide composition and corrosion resistance of the Al-containing 17Cr ODS steel in different concentrations of nitric acid were investigated by means of SEM, TEM, XPS and electrochemical methods. The corrosion result shows that with increasing concentration of 3 M–11.5 M HNO3, open circuit potential revealed nobler potential and the potentiodynamic polarization plots exhibited a shift in corrosion potential toward transpassive region. The boiling nitric acid test after 240 h exposed in 3 M–11.5 M HNO3 showed desirable corrosion rate of ∼0.075–0.25 mm/y. As the nitric acid concentration increased, the corrosion morphology varied from smaller pits to enlarged pits with groove-like features. The improved corrosion resistance of the ODS alloy is attributed to the alloy composition, nature of dispersed oxide and passive film nature, where Al2O3 is prominently enriched. The corrosion mechanisms of ODS steel is further discussed.



中文翻译:

含铝高铬铁素体分散增强钢在硝酸环境下的腐蚀行为

具有铁素体结构的含铬更高的17Cr氧化物弥散强化(ODS)钢(Fe-16.78Cr-4.46Al-0.5Ti-0.45Y 2 O 3 -0.36Y)是潜在的应用燃料覆层材料,适用于未来的高工作温度先进的核反应堆系统。通过SEM,TEM,XPS和电化学方法研究了不同浓度硝酸中含铝的17Cr ODS钢的显微组织,钝态氧化物组成和耐蚀性。腐蚀结果表明,随着HNO 3浓度的增加,其浓度为3 M–11.5 M,开路电势显示出更高的电势,并且电位动力学极化图显示出腐蚀电势向过钝区移动。在3 M–11.5 M HNO 3中暴露240 h后的沸腾硝酸测试显示,理想的腐蚀速率为〜0.075–0.25 mm / y。随着硝酸浓度的增加,腐蚀形态从较小的凹坑到具有槽状特征的扩大的凹坑变化。ODS合金的改进的耐腐蚀性归因于合金成分,分散的氧化物的性质和钝化膜的性质,其中Al 2 O 3明显富集。进一步讨论了ODS钢的腐蚀机理。

更新日期:2020-03-26
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