A series of novel meso- triazoloporphyrin-carborane conjugates was prepared in good yields via the copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction of Zn(II) or Pd(II) 5,10,15,20-tetrakis[4-(2-propargyloxy)-2,3,5,6-tetrafluorophenyl]porphyrin or Zn(II) 5,10,15,20-tetra(p-propargyloxyphenyl)porphyrin with 1-azidomethyl-o-carborane in CH₂Cl₂. Zinc metalloporphyrins were demetallated under acidic conditions to afford the corresponding free-base triazolo-carborane porphyrins in excellent yields. All new compounds were characterized by MS, NMR and UV–vis spectroscopy and their photophysical properties were studied.

通过铜（I）催化的锌（II）或钯（II）5,3,10,15,20-四烷基的惠斯根1,3-偶极环加成反应以高收率制备了一系列新型的内消旋-三唑并卟啉-碳硼烷共轭物[4-（2-炔丙氧基）-2,3,5,6-四氟苯基]卟啉或Zn（II）5,10,15,20-四（p -propargyloxyphenyl）卟啉与1- azidomethyl- ö -carborane在CH ₂ Cl ₂。将金属卟啉锌在酸性条件下脱金属，以优异的产率得到相应的游离碱三唑-碳硼烷卟啉。所有新化合物均通过MS，NMR和UV-vis光谱进行了表征，并对其光物理性质进行了研究。