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Reduced graphene oxide/SnO2 nanocomposites for the photocatalytic degradation of Rhodamine B: Preparation, characterization, photosensitization, vectorial charge transfer mechanism and identification of reaction intermediates
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-03-23 , DOI: 10.1016/j.cplett.2020.137385
R. Shyamala , L. Gomathi Devi

2 dimensional-reduced graphene oxide (RGO) was anchored on the surface of tin oxide (SnO2) to extend the absorption to visible region. Rutile structure is confirmed for SnO2 and RGO-SnO2. Partial reduction of graphene oxide to RGO is confirmed by infrared and Raman spectroscopic techniques. RGO-SnO2 shows 30% reduced recombination of charge carriers. The enhanced photocatalytic activity of RGO-SnO2 can be attributed to vectorial electron transfer process in the continuous network of RGO with large specific surface area, synergistic interaction between RGO and SnO2, unique double layer characteristics and photosensitization process. Major photocatalytic degradation reaction intermediates were identified by GC-MS technique.



中文翻译:

还原型氧化石墨烯/ SnO 2纳米复合物对罗丹明B的光催化降解:制备,表征,光敏化,矢量电荷转移机理和反应中间体的鉴定

将二维还原的氧化石墨烯(RGO)固定在氧化锡(SnO 2)的表面上,以将吸收扩展到可见光区域。SnO 2和RGO-SnO 2的金红石结构得到确认。通过红外和拉曼光谱技术证实了氧化石墨烯部分还原为RGO。RGO-SnO 2的载流子重组减少了30%。RGO-SnO 2的增强的光催化活性可归因于具有较大比表面积的RGO连续网络中的矢量电子转移过程,RGO与SnO 2之间的协同相互作用,独特的双层特性和光敏过程。通过GC-MS技术鉴定了主要的光催化降解反应中间体。

更新日期:2020-03-24
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