Abiotic Oxidase Reaction Cascades: An immobilized antimony‐oxo porphyrin derivative is applied as visible‐light driven photocatalyst promoting the aromatic hydroxylation of L ‐tyrosine, followed by a stepwise four‐electron oxidation to generate the natural product dopachrome. The biomimetic diphenolase activity of the artificial enzyme is comparable to native tyrosinase.

中文翻译：

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基于可见光控制的人造光酶的高效酪氨酸酶活性多电子氧化还原催化

非生物氧化酶反应级联：固定化的锑-氧卟啉衍生物用作可见光驱动的光催化剂，促进L-酪氨酸的芳族羟基化，然后逐步进行四电子氧化以生成天然产物多巴色素。人工酶的仿生双酚酶活性与天然酪氨酸酶相当。