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Electrophoretic Deposition of Chitosan-modified Carbon Fiber to Enhance Hygrothermal and Mechanical Properties of Carbon Fiber/Polyamide 6 Composites
Fibers and Polymers ( IF 2.5 ) Pub Date : 2020-03-22 , DOI: 10.1007/s12221-020-9280-6
Liping Li , Daoyi Wu , Min He

The surface of carbon fiber (CF) was modified by the electrophoretic deposition of cationic chitosan (CS), which is expected to enhance the hygrothermal and mechanical properties of carbon fiber/polyamide 6 (CF/PA 6) composites. Carbon fiber in various treatment stages was characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, atomic force microscopy, and X-ray diffraction. The studies demonstrate that the chitosan-modified carbon fiber (CS-CF) increases the surface chemical activity and roughness of carbon fiber, which enhances the chemical bonding and mechanical interlocking of carbon fiber with PA 6. Compared with desized carbon fiber (D-CF), the O/C composition ratio of CS-CF increased from 20.34 % to 50.86 %, and the tensile strength and flexural strength of the CS-CF/PA 6 composites were enhanced by 50.31 % and 43.88 %, respectively. In addition, the hygrothermal properties of CS-CF/PA 6 were also improved. Fracture observation of the composite cross-sections further elucidates the mechanism of interfacial strengthening.



中文翻译:

电泳沉积壳聚糖修饰的碳纤维以增强碳纤维/聚酰胺6复合材料的湿热和机械性能

碳纤维(CF)的表面通过阳离子型壳聚糖(CS)的电泳沉积进行了改性,有望增强碳纤维/聚酰胺6(CF / PA 6)复合材料的湿热性能和机械性能。通过傅里叶变换红外光谱,X射线光电子能谱,扫描电子显微镜,原子力显微镜和X射线衍射对碳纤维在不同处理阶段的特性进行了表征。研究表明,壳聚糖改性碳纤维(CS-CF)提高了碳纤维的表面化学活性和粗糙度,从而增强了碳纤维与PA 6的化学键合和机械互锁。 ),CS-CF的O / C组成比从20.34%增加到50.86%,CS-CF / PA 6复合材料的拉伸强度和弯曲强度分别提高了50.31%和43.88%。另外,CS-CF / PA 6的湿热性能也得到改善。复合截面的断裂观察进一步阐明了界面强化的机理。

更新日期:2020-04-21
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