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Extraction of carbon from waste cotton to efficiently carry tin oxide anodes
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-02-21 , DOI: 10.1007/s10854-020-03106-2
Jingyi Zou , Xiaogang Sun , Rui Li , Qiang He

Abstract

The difference in melting and boiling points between different materials is cleverly used, which the surface of tin oxide is coated with manganese oxide as a buffer layer, thereby suppressing the volume expansion. Considering that Li2O deposits will be generated during charge–discharge, which is not conducive to lithium ion insertion and causes irreversible capacity loss. Extraction of bio-carbon materials (BC) from waste cotton. The bio-carbon materials (BC) retains intact plant fibers and can effectively store electrolytes, improve lithium ion transmission rate, ensure electron conduction efficiency, and is also an excellent SnO2–Mn materials host. The SnO2–Mn@BC batteries prepared by combining the bio-carbon materials (BC) with the SnO2–Mn materials, which has excellent electrochemical performance, which the primary discharge specific capacity of electrode reached 2021.23mAh·g−1(current density of 100 mAh·g−1). After 100 cycles, the specific discharge capacity still maintained above 768.14 mAh·g−1 with a coulombic efficiency of 99.25%.



中文翻译:

从废棉中提取碳以有效携带氧化锡阳极

摘要

巧妙地利用了不同材料之间的熔点和沸点差,该氧化锡表面覆盖有氧化锰作为缓冲层,从而抑制了体积膨胀。考虑到在充放电过程中会生成Li 2 O沉积物,这不利于锂离子的插入并导致不可逆的容量损失。从废棉中提取生物碳材料(BC)。生物碳材料(BC)保留了完整的植物纤维,可以有效地存储电解质,提高锂离子的传输速率,确保电子传导效率,并且还是出色的SnO 2 -Mn材料宿主。通过将生物碳材料(BC)与SnO 2结合而制备的SnO 2 -Mn @ BC电池-Mn材料,具有优异的电化学性能,电极的一次放电比容量达到2021.23mAh·g -1(电流密度为100 mAh·g -1)。在100次循环之后,比放电容量仍保持在768.14mAh·g -1以上,库仑效率为99.25%。

更新日期:2020-03-22
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