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Study on different proportions of ferromanganese as an efficient mercury removal adsorbent: Role of external magnetic field
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-03-21 , DOI: 10.1016/j.cplett.2020.137392
Ping He , Xinyi Zhao , Yi Zhang , Huang Qin , Jie Wei , Tianhong Xu , Jiang Wu

In this paper, we used coprecipitation method to prepare different ratios of Mn/γ-Fe3O4 to remove Hg0. Different ratios of Mn and Fe could affect the mercury removal efficiency of Mn/γ-Fe3O4. The mechanism of Hg0 adsorption on the surface of Mn/γ-Fe3O4 matches the Mars-van Krevelen reaction mechanism. The catalytic oxidation of mercury on the surface of the sample is related to Fe and Mn. We also performed a pseudo-first-order kinetic model and an improved pseudo-n-order kinetic model. In addition, the external magnetic field has a certain promoting effect on the mercury removal.



中文翻译:

研究不同比例的锰铁作为一种有效的除汞吸附剂:外部磁场的作用

在本文中,我们使用共沉淀法制备了不同比例的 /γ--3Ø4去除Hg 0。Mn和Fe的不同比例会影响汞的去除效率。中号ñ/γ--FË3Ø4。Hg 0在金属表面吸附的机理中号ñ/γ--FË3Ø4与Mars-van Krevelen反应机制匹配。汞在样品表面的催化氧化与铁和锰有关。我们还执行了伪一阶动力学模型和改进的伪n阶动力学模型。另外,外部磁场对除汞有一定的促进作用。

更新日期:2020-03-22
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