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Recent Progress in Calix[n]quinone (n=4, 6) and Pillar[5]quinone Electrodes for Secondary Rechargeable Batteries
Batteries & Supercaps ( IF 5.7 ) Pub Date : 2020-03-20 , DOI: 10.1002/batt.202000038
Meng Zhang 1 , Yi Zhang 1 , Weiwei Huang 1, 2 , Qichun Zhang 2
Affiliation  

Attributing to the advantages of high theoretical specific capacity, good structural designability and environmental friendliness, organic quinone electrode materials have been applied in secondary batteries to achieve great electrochemical performances. At present, a series of researches about secondary batteries with quinone‐based compounds calix[4]quinone (C4Q), pillar[5]quinone (P5Q) and calix[6]quinone (C6Q) as cathodes have been carried out. In this review, we systematically summarize the applications of these three types of quinone compounds in lithium‐ion batteries (LIBs), sodium‐ion batteries (SIBs), zinc‐ion batteries (ZIBs), and magnesium‐ion batteries (Mg‐ion batteries). The optimizing methods for suppressing the dissolution of organic electrode materials such as quasi‐solid‐state electrolytes, all‐solid‐state electrolytes, ionic liquid electrolytes, aqueous electrolytes and carbon immobilization are concluded. This review could provide a good guideline to improve the electrochemical performances of secondary batteries using quinone compounds as cathodes in the future.

中文翻译:

杯形[n]醌(n = 4、6)和柱状[5]醌电极用于二次充电电池的最新进展

由于具有高的理论比容量,良好的结构设计能力和环境友好性的优点,有机醌电极材料已被用于二次电池中以实现优异的电化学性能。目前,对以醌类化合物杯[4]醌(C4Q),支柱[5]醌(P5Q)和杯[6]醌(C6Q)为正极的二次电池进行了一系列研究。在这篇综述中,我们系统地总结了这三种类型的醌类化合物在锂离子电池(LIB),钠离子电池(SIB),锌离子电池(ZIBs)和镁离子电池(Mg-ion)中的应用电池)。抑制有机电极材料(如准固态电解质,全固态电解质,总结了离子液体电解质,水性电解质和碳固定化。这篇综述可以为将来改进以醌类化合物为正极的二次电池的电化学性能提供很好的指导。
更新日期:2020-03-20
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