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Development of highly efficient bundle-like hydroxyapatite towards abatement of aqueous U(VI) ions: Mechanism and economic assessment.
Journal of Hazardous Materials ( IF 13.6 ) Pub Date : 2020-03-19 , DOI: 10.1016/j.jhazmat.2020.122550
Qingpu Shi 1 , Minhua Su 1 , Gutha Yuvaraja 1 , Jinfeng Tang 2 , Lingjun Kong 1 , Diyun Chen 1
Affiliation  

The exploration of emergency materials with ultra-fast adsorption rate and great adsorption capability of released U(VI) ions is essentially urgent. The present work successfully fabricated bundle-like hydroxyapatite (B-HAP) microstructures which composed of numerous nanorods by employing a facile and green method. The B-HAP was applied to treat the U(VI) containing wastewater. The abatement of U(VI) by B-HAP was very rapid and the saturated adsorption capacity was superior; over 96.7 % of U(VI) was abated within 5 min, and the maximum adsorption capacity was as high as to 1305 mg/g, signifying the feasibility and effectiveness of this B-HAP in the treatment of uranium-contaminated wastewater due to nuclear accidents. It is worthy to note that other ions in solution exhibited relatively low interference on its performance, indicating that B-HAP has great application potential to capture U(VI) from radioactive-contaminated wastewater as well. The U(VI) removal mechanism by B-HAP was confirmed with results from XRD, FT-IR and XPS. Chernikovite [H2(UO2)2(PO4)2·8H2O] was newly formed after U(VI) abatement by B-HAP. Economic assessment suggested B-HAP and its application on U(VI) abatement were cost-effective. With characteristics of high adsorption rate, large capacity, and strong antijamming ability, B-HAP has great application potential as an emergency treatment material for nuclear accidents.

中文翻译:

发展高效的束状羟基磷灰石以减少U(VI)水溶液离子:机理和经济评估。

具有超快吸附速率和强大的已释放U(VI)离子吸附能力的应急材料的研究迫在眉睫。目前的工作成功地制造了束状羟基磷灰石(B-HAP)的微结构,通过采用一种简便而环保的方法,由许多纳米棒组成。B-HAP用于处理含U(VI)的废水。B-HAP消除U(VI)的速度非常快,并且饱和吸附能力优异。在5分钟内消除了超过96.7%的U(VI),最大吸附容量高达1305 mg / g,这表明该B-HAP在处理核污染铀污染废水中的可行性和有效性事故。值得注意的是,溶液中的其他离子对其性能的干扰相对较低,表明B-HAP在从放射性污染废水中捕获U(VI)方面也具有巨大的应用潜力。XRD,FT-IR和XPS的结果证实了B-HAP去除U(VI)的机理。B-HAP消减U(VI)后,新形成了Chernikovite [H2(UO2)2(PO4)2·8H2O]。经济评估表明,B-HAP及其在减少U(VI)方面的应用具有成本效益。B-HAP具有吸附率高,容量大,抗干扰能力强等特点,作为核事故应急处理材料具有广阔的应用前景。经济评估表明,B-HAP及其在减少U(VI)方面的应用具有成本效益。B-HAP具有吸附率高,容量大,抗干扰能力强等特点,作为核事故应急处理材料具有广阔的应用前景。经济评估表明,B-HAP及其在减少U(VI)方面的应用具有成本效益。B-HAP具有吸附率高,容量大,抗干扰能力强等特点,作为核事故应急处理材料具有广阔的应用前景。
更新日期:2020-03-20
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