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NO and SO2 removal and pore structure evolution during reburning with calcium magnesium acetate blended peanut shell
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2019-06-14 , DOI: 10.1016/j.joei.2019.06.004
Lihui Zhang , Feng Duan , Xingrong Wu

Calcium magnesium acetate (CMA) was an effective material for the NO reduction and SO2 removal simultaneously by using reburning technology. To further improve its NO reduction rate, the peanut shell blended with CMA was used as the reburning fuels. Effects of the Ca/S molar ratio and temperature on the NO reduction and SO2 removal were investigated. Pore characteristics of solid samples at different temperatures were also studied. Results show that peanut shell addition improves the NO reduction and SO2 removal during the CMA reburning process. A Ca/S molar ratio ranging from 2 to 3 is a reasonable range for this technology. At lower temperatures, NO reduction and SO2 removal ratios are much smaller because of the poorly developed pore structure and tar blocking. With increases in temperature, both ratios increase significantly due to the well-developed pore structure caused by volatile matter release and CMA calcination. At a temperature of 900 °C, the SO2 removal ratio increases slowly because of the partial surface sintering of CaO and because some pores are blocked by the pollutants.



中文翻译:

醋酸钙镁混合花生壳再燃烧过程中NO和SO 2的去除及孔结构的演变

乙酸钙镁(CMA)是通过使用再燃烧技术同时减少NO和SO 2的有效材料。为了进一步提高其NO还原率,花生壳与CMA混合用作再燃燃料。研究了Ca / S摩尔比和温度对NO还原和SO 2去除的影响。还研究了固体样品在不同温度下的孔隙特征。结果表明,添加花生壳可改善CMA再燃过程中的NO还原和SO 2去除。Ca / S摩尔比在2到3之间是该技术的合理范围。在较低温度下,NO还原和SO 2由于不良的孔隙结构和焦油堵塞,去除率要小得多。随着温度的升高,由于挥发物释放和CMA煅烧导致孔隙结构发达,两个比率均显着增加。在900°C的温度下,由于CaO的部分表面烧结以及某些孔被污染物堵塞,SO 2的去除率缓慢增加。

更新日期:2019-06-14
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