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Phase equilibrium and liquid viscosity data for R-290/POE ISO 22 mixtures between 283 and 353 K
International Journal of Refrigeration ( IF 3.9 ) Pub Date : 2020-02-20 , DOI: 10.1016/j.ijrefrig.2020.02.029
Fernando F. Czubinski , Carlos J. Noriega Sanchez , Alexandre K. da Silva , Moisés A. Marcelino Neto , Jader R. Barbosa

Novel experimental data and theoretical calculations of bubble point pressure and liquid-phase viscosity for a propane (R-290)/POE ISO 22 binary system are presented. The experimental setup consisted of an oscillating-piston viscometer connected in series with a synthetic variable-volume PVT cell. Experimental data were acquired for R-290 with mole fractions ranging from 0.2 to 0.8, temperatures between 283 and 353 K and pressures up to 22.5 bar. The phase equilibrium (bubble point pressure) was modelled using the Peng and Robinson (1976) and PC-SAFT (Gross and Sadowski, 2001) equations of state, while the liquid mixture viscosity data were predicted with the generalized friction theory (f-theory) of Quiñones-Cisneros and Deiters (2006). The absolute average deviations associated with the phase equilibrium and liquid viscosity calculations were 8.39% and 6.56% (Peng-Robinson and PC-SAFT), and 24.77% (generalized f-theory).



中文翻译:

R-290 / POE ISO 22混合物在283和353 K之间的相平衡和液体粘度数据

提出了丙烷(R-290)/ POE ISO 22二元体系的新的实验数据和沸点压力和液相粘度的理论计算。实验装置包括与合成可变体积PVT电池串联的振荡活塞粘度计。获得了R-290的实验数据,其摩尔分数为0.2至0.8,温度在283至353 K之间,压力高达22.5 bar。使用Peng和Robinson(1976)和PC-SAFT(Gross and Sadowski,2001)状态方程对相平衡(气泡点压力)进行建模,而液体混合物的粘度数据则通过广义摩擦理论(f理论)进行预测。 )(Quinones-Cisneros and Deiters)(2006)。与相平衡和液体粘度计算相关的绝对平均偏差为8。

更新日期:2020-03-04
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