This mini review summarizes recent advances in experimental thermodynamics of metal–organic frameworks (MOFs). Taking advantage of the development in mechanochemistry, near-room temperature solution calorimetry, and low-temperature heat capacity measurements, the energetic landscape, entropy trends, and Gibbs free energy evolutions of MOFs with true polymorphism [Zn(MeIm)2, Zn(EtIm)2, and Zn(CF3Im)2] as framework topology varies were thoroughly explored by integrated calorimetric and computational methodologies. In addition, the formation enthalpies of MOFs with ultrahigh porosity (MOF-177 and UMCM-1) and the simplest structure (metal formates) have been determined. The studies summarized below highlight the complex interplays among interrelated compositional, chemical, and topological (structural) factors in the determination of the thermodynamic parameters of MOFs.

中文翻译：

---

金属-有机框架实验热力学的最新进展

这篇小型综述总结了金属有机框架 (MOF) 实验热力学的最新进展。利用机械化学、近室温溶液量热法和低温热容量测量的发展，具有真正多态性的 MOF 的能量景观、熵趋势和吉布斯自由能演化 [锌(MeIm)2,锌(EtIm)2， 和锌(CF3我是）2] 随着框架拓扑的变化，通过集成的量热和计算方法进行了彻底的探索。此外，超高孔隙度 MOF 的形成焓 (财政部-177 和UMCM-1) 和最简单的结构 (金属甲酸盐) 已确定。下面总结的研究强调了在确定 MOF 的热力学参数时相互关联的成分、化学和拓扑（结构）因素之间的复杂相互作用。