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Tiny Ni0.85Se nanosheets modified by amorphous carbon and rGO with enhanced electrochemical performance toward hybrid supercapacitors
Journal of Energy Storage ( IF 9.4 ) Pub Date : 2020-03-13 , DOI: 10.1016/j.est.2020.101348
Zhiying Sun , Fulong Liu , Jiahui Wang , Yuanning Hu , Yuhang Fan , Shina Yan , Jiaqin Yang , Lirong Xu

Considering that electrode materials for supercapacitors suffer poor cycling stability and low electrons transfer at high current density, combination with carbonaceous materialhas has been devoted to strengthen the conductivity and improve the specific power and specific energy. Herein, the Ni0.85Se@C/rGO composite with tiny Ni0.85Se nanosheeets anchoring on rGO and coated by amorphous carbon has been successfully synthesized via programmed temperature controlling. As combined with dual modified carbon, which not only can ensure the electric connection of all the tiny Ni0.85Se nanosheets, but also provide confinement to inhibit disintegration, the Ni0.85Se@C/rGO//AC supercapacitor device shows a thrilling specific energy of 45.6 Wh kg−1 and 31.4 Wh kg−1 at specific power of 463.5 W kg−1 and 9.4 kW kg−1, respectively.



中文翻译:

非晶碳和rGO修饰的Ni0.85Se纳米薄片,对混合超级电容器具有增强的电化学性能

考虑到用于超级电容器的电极材料具有差的循环稳定性和在高电流密度下的低电子传递,已经致力于与碳质材料的结合以增强电导率并提高比功率和比能量。在此,通过程序控制的温度已经成功地合成了Ni 0.85 Se @ C / rGO复合材料,该复合材料具有固定在rGO上并由无定形碳包覆的微小Ni 0.85 Se纳米片。与双重改性碳结合使用,不仅可以确保所有微小的Ni 0.85 Se纳米片的电连接,而且还可以提供限制作用以抑制崩解,Ni 0.85Se @ C / rGO // AC超级电容器装置在463.5 W kg -1和9.4 kW kg -1的比功率下分别显示出45.6 Wh kg -1和31.4 Wh kg -1的惊险比能。

更新日期:2020-03-13
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