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Fabrication of hybrid supercapacitor device based on NiCo2O4@ZnCo2O4 and the biomass-derived N-doped activated carbon with a honeycomb structure
Electrochimica Acta ( IF 6.6 ) Pub Date : 2020-03-17 , DOI: 10.1016/j.electacta.2020.136062
A. Juliet Christina Mary , C.I. Sathish , Paskalis Sahaya Murphin Kumar , Ajayan Vinu , A. Chandra Bose

Highly efficient supercapacitor devices are fabricated with the hybrid nanocomposite material and biomass-derived N-doped activated carbon with tunable morphology, composition and structures. NiCo2O4 materials with different morphologies including spherical, urchin, rod and granular are synthesized using different surfactants. These electrode materials display the maximum specific capacity of 419, 543, 506, and 456 C g−1 at 1 A g−1 respectively in 2 M KOH. The optimized urchin-like NiCo2O4 is hybridized with different concentration of ZnCo2O4 nanosheets. The hybridization process significantly increased the specific capacity to 1029 C g−1 at 1 A g−1 for NiCo2O4@ZnCo2O4-2 (NZC2). In order to make the hybrid supercapacitor device, honeycomb porous structured N-doped activated carbon is prepared with the Ricinus communis seed. The prepared material shows an interconnected pore structure with a high nitrogen content and exhibits the maximum specific capacity of 236 C g−1 at a current density of 1 A g−1. The hybrid supercapacitor device made from NZC2 and the N-doped activated carbon offers the highest energy density of 101.6 W h kg−1 with the corresponding power density of 1.62 kW kg−1.



中文翻译:

基于NiCo 2 O 4 @ZnCo 2 O 4和蜂窝状生物质衍生的N掺杂活性炭的混合超级电容器装置的制备

用杂化的纳米复合材料和具有可调形态,组成和结构的生物质衍生的N掺杂活性炭制造高效的超级电容器。使用不同的表面活性剂合成了具有球形,野孩子,棒状和颗粒状不同形态的NiCo 2 O 4材料。这些电极材料在2 M KOH中分别在1 A g -1下显示出最大比容量419、543、506和456 C g -1。优化的海胆状镍钴2 ö 4杂交用不同浓度的碳酸锌的2 ö 4纳米片。杂交过程的比容量显著增加至1029 C g还-1 1 A G -1为镍钴2 ö 4 @ZnCo 2 ø 4 -2(NZC2)。为了制造混合超级电容器装置,用蓖麻种子制备蜂窝状多孔结构的N掺杂活性炭。所制备的材料显示出具有高氮含量的互连孔结构,并且在1A g -1的电流密度下显示出236 C g -1的最大比容量。由NZC2和N掺杂活性炭制成的混合超级电容器装置提供的最高能量密度为101.6 W h kg -1对应的功率密度为1.62 kW kg -1

更新日期:2020-03-19
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