A novel, rational‐designed approach to access various heteroaryl‐substituted alkyl thioethers was developed via docking‐migration cascade process. By utilizing three components involving alkene, dual‐function reagent, and thioetherificating reagent, radical heteroarylalkylation of alkenes followed by thiolation of the alkyl radical intermediates proceeded smoothly, manifesting well compatibility of substrates and cascade transformations. Furthermore, this protocol also features mild conditions, broad substrate scope, and wide product diversity.

中文翻译：

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三组分对接迁移硫醚化级联反应使烯烃自由基杂芳基烷基化

通过对接迁移级联过程，开发了一种新颖的，合理设计的方法来访问各种杂芳基取代的烷基硫醚。通过利用涉及烯烃，双功能试剂和硫醚化试剂的三种组分，烯烃的自由基杂芳基烷基化以及烷基自由基中间体的硫醇化进展顺利，表明底物和级联转化具有良好的相容性。此外，该协议还具有温和的条件，广泛的底物范围和广泛的产品多样性。