Polyoxometalates (POMs) are interesting clusters that attracted great attention due to their remarkable structures and intriguing applications. The incorporation of POMs into crystalline architectures generates functional hybrid materials because such materials combine the merits of POMs and architectures together, thus deriving special properties. In particular, the unique combination of POMs with currently popular architectures, viz. Metal-Organic Frameworks (MOFs), Covalent-Organic Frameworks (COFs) and metallosupramolecules, received great development. In this review, the synthetic strategies, classification and functional properties of POM-based architectures are summarized. Moreover, the current challenges in the design, synthesis and property investigation of POM-based architectures are also discussed.

多金属氧酸盐（POM）是有趣的簇，由于其出色的结构和有趣的应用而引起了极大的关注。将POM合并到晶体结构中会生成功能性混合材料，因为此类材料将POM和结构的优点结合在一起，从而获得特殊的性能。特别是，POM与当前流行的体系结构的独特结合。金属有机框架（MOF），共价有机框架（COF）和金属超分子都得到了长足的发展。在这篇综述中，总结了基于POM的体系结构的综合策略，分类和功能特性。此外，还讨论了基于POM的体系结构的设计，综合和性能研究方面的当前挑战。