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Discovery of supercritical carbon dioxide in a hydrothermal system
Science Bulletin ( IF 18.9 ) Pub Date : 2020-03-14 , DOI: 10.1016/j.scib.2020.03.023
Xin Zhang , Lian-Fu Li , Zeng-Feng Du , Xi-Luo Hao , Lei Cao , Zhen-Dong Luan , Bing Wang , Shi-Chuan Xi , Chao Lian , Jun Yan , Wei-Dong Sun

Supercritical CO2 appearing as bubbles in hydrothermal vents was identified in the south part of the Okinawa Trough using in situ Raman spectroscopy. Significantly, the N2 peak in supercritical CO2 is much larger than those in seawater and vent fluids, indicating that supercritical CO2 enriches N2 from the surrounding environment. Considering that the partial pressures of CO2 and N2 in the Earth’s proto-atmosphere were ~10–20 MPa, supercritical CO2 with high N2 was likely the dominant CO2 phase near the water-air interface in the early history of the Earth, which promoted the synthesis, pre-enrichment and preservation of amino acids and other organic matters that are essential to the origin of life.



中文翻译:

在水热系统中发现超临界二氧化碳

使用原位拉曼光谱法在冲绳海槽的南部发现了在热液喷口中以气泡形式出现的超临界CO 2。显著中,N 2在超临界CO峰2是比在海水大得多和泄流体,表明超临界二氧化碳2的丰富Ñ 2从周围环境中。考虑到地球原始大气中CO 2和N 2的分压为〜10–20 MPa,N 2高的超临界CO 2可能是主要的CO 2 在地球的早期历史中,水-空气界面附近有一个阶段,促进了生命起源必不可少的氨基酸和其他有机物质的合成,预富集和保存。

更新日期:2020-03-14
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