当前位置: X-MOL 学术Organometallics › 论文详情
CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases
Organometallics ( IF 3.804 ) Pub Date : 2020-03-12 , DOI: 10.1021/acs.organomet.9b00838
Jerik Mathew Valera Lauridsen; Sung Yeon Cho; Han Yong Bae; Ji-Woong Lee

Carbon dioxide (CO2) is an intrinsically stable molecule. However, its reactivity toward nucleophilic bases has constituted an appealing characteristic for applications such as CO2 capture and functionalization. To shed light on the role of nucleophilic bases in CO2 functionalization, we performed some mechanistic studies using nitrogen-containing bases as an additive—in catalytic amounts—for carboxylation reactions of Grignard reagents. Our kinetic analysis and in situ infrared spectroscopy revealed the role of nucleophilic bases, particularly that of DBU (1,8-diazabicycloundec-7-ene), in CO2 (de)activation for carboxylation reactions.
更新日期:2020-03-12

 

全部期刊列表>>
欢迎访问IOP中国网站
自然职场线上招聘会
GIANT
产业、创新与基础设施
自然科研线上培训服务
材料学研究精选
胸腔和胸部成像专题
屿渡论文,编辑服务
何川
苏昭铭
陈刚
姜涛
李闯创
李刚
北大
隐藏1h前已浏览文章
课题组网站
新版X-MOL期刊搜索和高级搜索功能介绍
ACS材料视界
天合科研
x-mol收录
上海纽约大学
陈芬儿
厦门大学
何振宇
史大永
吉林大学
卓春祥
张昊
杨中悦
试剂库存
down
wechat
bug