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Structures and UV resistance of Ag/SnO2 nanocomposite materials synthesized by horizontal vapor phase growth for coating applications
Journal of Materials Research and Technology ( IF 6.4 ) Pub Date : 2020-03-11 , DOI: 10.1016/j.jmrt.2020.03.001
Eduardo B. Tibayan , Muhammad Akhsin Muflikhun , Al Rey C. Villagracia , Vipin Kumar , Gil Nonato C. Santos

The structures and UV resistance of Ag/SnO2 nanocomposite materials was observed in this study for coating applications. Horizontal Vapor Phase Growth (HVPG) was used to synthesize the Ag/SnO2 nanocomposite materials. The ratio between Ag and SnO2 was fixed with stoichiometric mixtures of 0:5, 1:4, 2:3, 3:2, 4:1, and 5:0. Scanning electron microscope–energy-dispersive X-ray spectroscopy (SEM–EDX) was used to evaluate the morphology of the materials. The results were then compared with Density Functional Theory (DFT) analysis. Computational DFT analysis of the SnO2 (110) and Ag (111) cells have verified nanorods formation of the composite material. Moreover, DFT results of Ag/SnO2 confirmed the UV blocking properties from their computed electrical bandgap energies of the range from 2.72 to 4.84 eV. The highest UV absorbance of nanocomposite was observed for 1:4 Ag/SnO2 stoichiometric ratio with 8.09 A. The study shows that the ration of SnO2 over Ag increases, the absorbance increases as well.



中文翻译:

通过水平气相生长合成的Ag / SnO 2纳米复合材料的结构和抗紫外线性能

在这项研究中,观察到了Ag / SnO 2纳米复合材料的结构和抗紫外线性能。使用水平气相生长(HVPG)合成Ag / SnO 2纳米复合材料。用0:5、1:4、2:3、3:2、4:1和5:0的化学计量混合物固定Ag和SnO 2之间的比例。扫描电子显微镜–能量色散X射线光谱(SEM–EDX)用于评估材料的形貌。然后将结果与密度泛函理论(DFT)分析进行比较。SnO 2(110)和Ag(111)电池的计算DFT分析已验证了复合材料的纳米棒形成。此外,Ag / SnO 2的DFT结果通过计算得出的2.72至4.84 eV的带隙能,证实了紫外线阻隔性能。在化学计量比为1:4的Ag / SnO 2和8.09 A的情况下,观察到纳米复合材料的最高UV吸收率。研究表明SnO 2与Ag的比例增加,吸收率也增加。

更新日期:2020-03-12
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