Uranyl–carbon bonds are rare due to the limited numbers of synthetic routes. The synthesis of carbodicarbene uranyl complexes is reported, along with complete spectroscopic and structural characterization. These data along with a computational analysis confirm strong electron donation by the carbodicarbene ligand, as well as a single-bond order between the uranium(VI) ion and the carbon.

中文翻译：

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具有碳二碳配体的有机金属铀酰配合物

由于合成途径数量有限，因此铀酰-碳键很少见。报告了碳二碳烯铀酰配合物的合成，以及完整的光谱和结构表征。这些数据以及计算分析证实了碳二碳烯配体的强电子给定，以及铀（VI）离子与碳之间的单键顺序。