Na2MnIII6LnIII clusters with a non-equivalent core: chiral vs. meso isomerism,Dalton Transactions

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Na2MnIII6LnIII clusters with a non-equivalent core: chiral vs. meso isomerism
Dalton Transactions ( IF 4 ) Pub Date : 2020/03/10 , DOI: 10.1039/d0dt00540a
Júlia Mayans _{1,

2,

3,

4,

5} , Mercè Font-Bardia _{3,

6,

7,

8,

9} , Albert Escuer _{1,

2,

3,

4,

5}

Affiliation

A wide family of clusters with the Na₂Mn^III₆Ln^III core derived from an enantiomerically pure or a racemic mixture of Schiff bases lead to the characterization of a unique case of chiral/meso isomers with C₃/D_3d symmetry respectively, involving the rearrangement of the cluster bond parameters and the change from hepta- to hexacoordination of the central Ln^III cation.

中文翻译：

Na2MnIII6LnIII簇具有不等价的核：手性与内消旋异构

具有席夫碱纯对映异构体或消旋混合物的Na ₂ Mn ^III₆ Ln ^III核的大量簇簇导致分别表征C ₃ / D _3d对称的手性/内消旋异构体的独特情况，包括团簇键参数的重排以及中心Ln ^III阳离子从七配位到六配位的变化。

更新日期：2020-04-08

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