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Water does not catalyze the reaction of OH radicals with ethanol
Physical Chemistry Chemical Physics ( IF 3.3 ) Pub Date : 2020/03/05 , DOI: 10.1039/d0cp00467g
Isabelle Weber 1, 2, 3, 4, 5 , Hichem Bouzidi 1, 5, 6, 7, 8 , Bianca Krumm 1, 2, 3, 4, 5 , Coralie Schoemaecker 1, 2, 3, 4, 5 , Alexandre Tomas 1, 5, 6, 7, 8 , Christa Fittschen 1, 2, 3, 4, 5
Affiliation  

Recent experiments suggested that water catalyzes the reaction of OH radicals with alcohols, while another work showed the opposite result. Here, we resolve this disagreement and show that heterogeneous oxidation systematically biased the work showing the catalytic effect and corroborate that water does not catalyze the reaction of OH with alcohols.

中文翻译:

水不会催化OH自由基与乙醇的反应

最近的实验表明,水可以催化OH自由基与醇类的反应,而另一项工作却显示出相反的结果。在这里,我们解决了这个分歧,并表明多相氧化系统地偏置了显示催化作用的工作,并证实了水不能催化OH与醇的反应。
更新日期:2020-04-08
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