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Phenothiazine dyes containing a 4-phenyl-2-(thiophen-2-yl) thiazole bridge for dye-sensitized solar cells
Tetrahedron ( IF 2.1 ) Pub Date : 2020-03-05 , DOI: 10.1016/j.tet.2020.131102
Liang Han , Yaqian Chen , Jin’ge Zhao , Yanhong Cui , Shaoliang Jiang

Two novel phenothiazine dyes bearing a single or double cyanoacrylic acid acceptors, which share the same electron donor phenothiazine and the same 4-phenyl-2-(thiophen-2-yl)thiazole π-bridge, were synthesized. Thus, phenothiazine dyes with D-π-A and A-D-π-A framework were configured, and their photophysical properties and photovoltaic performance were investigated. The incorporation of another cyanoacrylic acid acceptor was found to benefit the loading amount on TiO2, the light-harvesting ability, and the electron-injection efficiency. Dye with double cyanoacrylic acid acceptors showed a double short-circuit current compared with dye with a single acceptor. Therefore, dye with double cyanoacrylic acid acceptors achieved improved photoelectric conversion efficiency 4.35% (JSC = 10.29 mA cm−2, VOC = 0.65 V, FF = 0.65) under standard global AM 1.5 G solar condition with dye N719 (7.19%) as a reference.



中文翻译:

含4-苯基-2-(噻吩-2-基)噻唑桥的吩噻嗪染料用于染料敏化太阳能电池

合成了两种带有一个或两个氰基丙烯酸受体的新型吩噻嗪染料,它们共享相同的电子给体吩噻嗪和相同的4-苯基-2-(噻吩-2-基)噻唑π-桥。因此,构造了具有D-π-A和AD-π-A骨架的吩噻嗪染料,并对其光物理性质和光电性能进行了研究。发现掺入另一种氰基丙烯酸受体有利于TiO 2上的负载量,光收集能力和电子注入效率。与具有单受体的染料相比,具有双氰基丙烯酸受体的染料显示出两倍的短路电流。因此,具有双氰基丙烯酸受体的染料的光电转换效率提高了4.35%(J SC 在标准的全球AM 1.5 G太阳条件下,染料N719(7.19%)为 10.29 mA cm -2V OC = 0.65 V,FF = 0.65)。

更新日期:2020-03-05
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