The synergetic interaction of solid solutions plays important roles in the reaction efficiency of CO₂ hydrogenation, which is used to produce methanol. The effects of material mixing, impregnation, traditional coprecipitation, and microreaction synthesis on the structural and catalytic properties of ZnO/t-ZrO₂ hybrid oxides were investigated. Although the impregnation effect caused a certain electronic structural modulation at the Zn/Zr interface, the pore structure blocking effect and low number of oxygen vacancy defects leaded to a low catalytic reaction efficiency. The solid solution structure enhanced the Zn/Zr interfacial interaction and increased the electron binding energy. More importantly, many oxygen vacancy defects were formed, which promoted CO₂ activation. However, the solid solution structure was more affected by the preparation method. The solid solution formed from the microreaction exhibited excellent catalytic activity, thermal stability and regeneration performance due to a more uniform solid solution structure and abundant oxygen vacancy defects. The CO₂ conversion rate, methanol selectivity, and methanol space-time yield (STY) under the conditions of H₂/CO₂ = 3:1, 320 °C, 3 MPa, GHSV = 12000 ml g^-1 h^-1 reached 9.2%, 93.1%, and 0.35 g_MeOH h^-1g_cat^-1, respectively.

固溶体的协同相互作用在用于生产甲醇的CO ₂加氢反应效率中起着重要作用。研究了材料混合，浸渍，传统的共沉淀和微反应合成对ZnO / t-ZrO ₂杂化氧化物的结构和催化性能的影响。尽管浸渍作用在Zn / Zr界面上引起了一定的电子结构调节，但是孔结构的阻断作用和氧空位缺陷的数量少导致催化反应效率低。固溶体结构增强了Zn / Zr界面相互作用并增加了电子结合能。更重要的是，形成了许多氧空位缺陷，从而促进了CO ₂激活。然而，固溶体结构受制备方法的影响更大。由于更均匀的固溶体结构和大量的氧空位缺陷，由微反应形成的固溶体表现出优异的催化活性，热稳定性和再生性能。该CO ₂的转化率，甲醇的选择性，及H的条件下，甲醇的时空产率（STY）₂ / CO ₂  = 3：1，320℃，3MPa的，GHSV =12000毫升克^-1  ħ ^-1达到分别为9.2％，93.1％和0.35 g _MeOH  h ^-1 g _cat ^-1。