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Promotion effect of nickel loaded on CdS for photocatalytic H2 production in lactic acid solution
Applied Surface Science ( IF 6.7 ) Pub Date : 2014-10-01 , DOI: 10.1016/j.apsusc.2014.08.053
Shu Chen , Xiaoping Chen , Qizhong Jiang , Jian Yuan , Caifang Lin , Wenfeng Shangguan

Abstract Low-cost Ni modified CdS was prepared via a hydrothermal reduction method. The hydrogen production activity of CdS loaded with 5 wt% Ni under visible light was even higher than that of the one loaded with 0.5 wt% Pt. The highest H 2 evolution rate (3004.8 μmol h −1 ) occurred when the concentration of sacrificial agent (lactic acid) was 50 vol%. The nickel can quickly transfer excited electrons and enhance the photocatalytic H 2 production activity. It was also found that the hydrogen evolution in this system was generated steadily from both water and lactic acid.

中文翻译:

CdS负载镍对乳酸溶液光催化制氢的促进作用

摘要 采用水热还原法制备了低成本的Ni改性CdS。在可见光下负载 5 wt% Ni 的 CdS 的产氢活性甚至高于负载 0.5 wt% Pt 的产氢活性。当牺牲剂(乳酸)的浓度为 50 vol% 时,H 2 的释放速率最高(3004.8 μmol h -1 )。镍能快速转移受激电子,提高光催化产氢活性。还发现该系统中的析氢是由水和乳酸稳定产生的。
更新日期:2014-10-01
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