Abstract High temperature tensimetry data on homogeneous gas phase dissociation of donor-acceptor complexes of group 13–15 metal halides have been analyzed. Thermodynamic characteristics and heat capacities have been computed by DFT methods. Standard dissociation enthalpies and standard formation enthalpies of gaseous donor-acceptor complexes have been obtained by combination of experimental and computational data with accounting for the heat capacity change.

中文翻译：

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通过考虑气相解离过程的热容差异得出的气相分子复合物的标准形成焓：重新审视实验张力测定数据

摘要 分析了第 13-15 族金属卤化物的供体-受体配合物的均相气相离解的高温张力测定数据。热力学特性和热容量已通过 DFT 方法计算。通过结合实验和计算数据并考虑热容变化，已经获得了气态供体-受体复合物的标准解离焓和标准形成焓。