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Single-component, low molecular weight organic supergelators based on chiral barbiturate scaffolds
Supramolecular Chemistry ( IF 3.3 ) Pub Date : 2019-06-16 , DOI: 10.1080/10610278.2019.1629437
Daniel T. Seidenkranz 1 , Kurt A. Langworthy 2 , Lev N. Zakharov 2 , Michael D. Pluth 1
Affiliation  

ABSTRACT We report here the first chiral barbiturate to act as a single-component LMOG capable of gelating a variety of chlorinated and aromatic solvents. Solution-based DOSY NMR experiments, solid-state VP-SEM, and X-ray crystallography techniques were used to characterize chloroform-based gels at a variety of size domains. This scaffold provides a simple system to study the dynamics of gelation and self-assembly. Graphical abstract

中文翻译:

基于手性巴比妥酸盐支架的单组分、低分子量有机超凝胶剂

摘要 我们在此报告了第一种手性巴比妥酸盐作为单组分 LMOG,能够胶凝各种氯化和芳香溶剂。基于溶液的 DOSY NMR 实验、固态 VP-SEM 和 X 射线晶体学技术用于表征各种尺寸域的基于氯仿的凝胶。该支架提供了一个简单的系统来研究凝胶化和自组装的动力学。图形概要
更新日期:2019-06-16
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