ABSTRACT In the solid state, uranyl-salophen complex 1, decorated with bipyridyl sidearms, self-assembles from moist acetonitrile into dimeric species displaying a confined water pentamer, as observed by X-ray diffraction on single crystals. The linear water cluster is incarcerated within the dimeric cavity by coordination to the Lewis acidic uranyl centres and by a network of hydrogen bonds established with the pyridinic nitrogen atoms on the sidearms. GRAPHICAL ABSTRACT

中文翻译：

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将线性水五聚体包埋到固态双铀酰-沙洛芬二聚体中

摘要 在固态下，双吡啶基侧臂装饰的铀酰-salophen 络合物 1 从潮湿的乙腈自组装成二聚体，显示出受限水五聚体，如通过单晶的 X 射线衍射观察到的。通过与路易斯酸性双氧铀中心的配位以及与侧臂上的吡啶氮原子建立的氢键网络，线性水团簇被嵌在二聚体腔内。图形概要