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A CoMn2O3.5-RGO hybrid as an effective Fenton-like catalyst for the decomposition of various dyes
New Carbon Materials ( IF 5.7 ) Pub Date : 2020-02-27 , DOI: 10.1016/s1872-5805(19)60030-2
Jiang-ying Qu , Zhi-qiang Yu , Yun-hao Zang , Jian-feng Gu , Ju-tao Jin , Feng Gao

A reduced graphene oxide (RGO)-supported CoMn2O3.5 composite (CoMn2O3.5-RGO) was synthesized by a coprecipitation method in a GO suspension using Co(NO3)2·6H2O and MnSO4·H2O as Co and Mn sources, respectively, followed by heat treatment at 600oC for 0.5 h. Results indicate that CoMn2O3.5 particles with an average diameter of about 300 nm decorated the RGO sheets and self-organized into microcubes. The C CoMn2O3.5-RGO as a Fenton-like catalyst exhibited the high activities for the decomposition of various dyes including methylene blue (MB), rhodamine B (RhB) and golden orange II (OGII). 10 mL solutions of the OGII, MB and RhB dyes (50 mg L−1) are 100% decolorized with 5 mg of the CoMn2O3.5/RGO in 50, 70 and 80 min, respectively. The high activity of the catalyst is closely related to a synergistic effect of RGO and CoMn2O3.5, where the dyes are adsorbed on the surface of RGO by interaction and retained in close proximity to the active sites of CoMn2O3.5.



中文翻译:

CoMn 2 O 3.5 -RGO杂化物作为有效的Fenton类催化剂,可分解各种染料

采用Co(NO 32 ·6H 2 O和MnSO 4 ·H 2 O共沉淀法在GO悬浮液中合成了还原氧化石墨烯(RGO)负载的CoMn 2 O 3.5复合材料(CoMn 2 O 3.5 -RGO)。分别作为Co和Mn源,然后在600 o C热处理0.5 h。结果表明,平均直径约为300 nm的CoMn 2 O 3.5颗粒装饰了RGO片并自组织成微立方体。C CoMn 2 O 3.5-RGO作为类Fenton催化剂,对包括亚甲基蓝(MB),若丹明B(RhB)和金橙II(OGII)在内的各种染料具有很高的分解活性。OGII,MB和RhB染料的10 mL溶液(50 mg L -1)分别在50、70和80分钟内分别用5 mg的CoMn 2 O 3.5 / RGO进行100%脱色。催化剂的高活性与RGO和CoMn 2 O 3.5的协同效应密切相关,其中染料通过相互作用吸附在RGO的表面,并保留在CoMn 2 O 3.5的活性位点附近。

更新日期:2020-02-27
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