In this Account, we provide an overview of our recent advances in oxidative transformations that enable the introduction of nitrogen and oxygen functionalities into organic molecules by taking advantage of the unique characteristics of iodine-based reagents, such as hypervalency, soft Lewis acidity, high leaving ability, and radical reactivity. We also report on the development of new types of hypervalent iodine reagents containing a transferable nitrogen functional group with the objective of preparing primary amines, which is described in the latter part of this Account. 1 Introduction 2 Decarboxylative Functionalization of β,γ-Unsaturated Carboxylic Acids 3 Decarboxylative Functionalization at Tertiary Carbon Centers 4 C–H Bond Functionalization at Tertiary Carbon Centers 5 Intramolecular C–H Amination of Sulfamate Esters and N-Alkylsulfamides 6 Oxidative Amination with Hypervalent Iodine Reagents Containing Transferable Nitrogen Functional Groups 7 Summary and Outlook

中文翻译：

---

氧化胺化和氧化中的碘基试剂

在本报告中，我们概述了我们在氧化转化方面的最新进展，这些进展利用碘基试剂的独特特性，例如高价、软路易斯酸度、高离去率，从而能够将氮和氧官能团引入有机分子中。能力和自由基反应性。我们还报告了含有可转移氮官能团的新型高价碘试剂的开发，其目的是制备伯胺，这将在本帐户的后半部分进行描述。1 引言 2 β 的脱羧功能化，