ABSTRACT Advances in evolved gas analysis (EGA) techniques are periodically reported by our group to provide useful examples of their applications in many different fields. It is actually recognized that anytime is requested a correct interpretation of the thermally induced reaction mechanism, involving the formation of gaseous species, it is strongly recommended the characterization of the evolved products. In this review, recent applications of mass spectrometry for EGA (EGA–MS), selected among those published in 2016 and 2017, are reported to show how the characterization of the nature of volatile products released by a substance subjected to a controlled temperature program allows to prove a supposed reaction, either under isothermal or under heating conditions.

中文翻译：

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用于逸出气体分析的质谱：更新

摘要 我们小组定期报告逸出气体分析 (EGA) 技术的进展，以提供其在许多不同领域中应用的有用示例。实际上，任何时候都需要正确解释热诱导反应机制，包括气态物质的形成，强烈建议对演化产物进行表征。在这篇综述中，从 2016 年和 2017 年发表的那些中选出的 EGA 质谱 (EGA-MS) 的最新应用被报道，以显示受控制温度程序的物质释放的挥发性产品的性质的表征如何允许在等温或加热条件下证明假设的反应。