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Catalytic formation of luminescent lanthanide complexes using an entropy-driven DNA circuit
Chemical Communications ( IF 4.9 ) Pub Date : 2020/02/26 , DOI: 10.1039/d0cc00602e
Yusuke Kitamura 1, 2, 3, 4, 5 , Yukina Azuma 1, 2, 3, 4, 5 , Yousuke Katsuda 1, 2, 3, 4, 5 , Toshihiro Ihara 1, 2, 3, 4, 5
Affiliation  

Two DNA conjugates modified with ethylenediaminetetraacetic acid and 1,10-phenanthroline were prepared as a pair of split probes. They were designed to form a duplex with their auxiliary groups facing each other, providing a microenvironment to accommodate lanthanide ions. The luminescent signal was amplified by catalytic duplex formation based on an entropy-driven DNA circuit.

中文翻译:

使用熵驱动的DNA回路催化形成发光镧系元素

制备了用乙二胺四乙酸和1,10-菲咯啉修饰的两个DNA偶联物,作为一对分离探针。它们被设计为形成一个双链体,其辅助基团彼此面对,从而提供了一个可容纳镧系元素离子的微环境。通过基于熵驱动的DNA电路的催化双链体形成来放大发光信号。
更新日期:2020-04-03
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