The novel formate oxidase from Aspergillus oryzae (AoFOx) is a useful catalyst to promote H₂O₂‐dependent oxyfunctionalisation reactions. In this contribution we exploit the substrate promiscuity of AoFOx to fully oxidise methanol and formaldehyde to CO₂ and drive peroxygenase‐catalysed stereoselective oxyfunctionalisation reactions. The highly atom efficient H₂O₂ generation system also enabled high catalytic turnover of the peroxygenase production enzyme.

中文翻译：

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FOx新闻：迈向甲醇驱动的生物催化氧官能化反应

米曲霉（Ao FOx）的新型甲酸氧化酶是促进H ₂ O ₂依赖性氧官能化反应的有用催化剂。在这项贡献中，我们利用了Ao FOx的底物混杂性将甲醇和甲醛完全氧化为CO _2，并驱动过氧合酶催化的立体选择性氧化官能化反应。高度原子高效的H ₂ O ₂生成系统还使过氧化酶生产酶的催化转化率更高。