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Reference Correlation for the Viscosity of Cyclopentane from the Triple Point to 460 K and up to 380 MPa
Journal of Physical and Chemical Reference Data ( IF 4.3 ) Pub Date : 2019-12-01 , DOI: 10.1063/1.5128321
K. A. Tasidou 1 , M. L. Huber 2 , M. J. Assael 1
Affiliation  

This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.This paper presents a new wide-ranging correlation for the viscosity of cyclopentane based on critically evaluated experimental data. The correlation is designed to be used with a recently developed equation of state, and it is valid from the triple point to 360 K in the liquid range up to 380 MPa and 460 K in the low-pressure vapor range. The average absolute percent deviation of the fit for all primary data is 0.8% with a bias of −0.3%. The estimated expanded uncertainty of the whole fit is 2.7% (at the 95% confidence level), while the uncertainty near atmospheric pressure from 298 K to 460 K increases to 4%. The correlation behaves in a physically reasonable manner when extrapolated to 500 MPa; however, care should be taken when using the correlations outside of the validated range.

中文翻译:

环戊烷粘度从三点到 460 K 和高达 380 MPa 的参考相关性

本文基于严格评估的实验数据,提出了一种新的广泛的环戊烷粘度相关性。该相关性旨在与最近开发的状态方程一起使用,它在高达 380 MPa 的液体范围内从三相点到 360 K 和低压蒸汽范围内的 460 K 有效。所有主要数据拟合的平均绝对百分比偏差为 0.8%,偏差为 -0.3%。整个拟合的估计扩展不确定性为 2.7%(在 95% 的置信水平下),而大气压附近从 298 K 到 460 K 的不确定性增加到 4%。当外推到 500 MPa 时,相关性表现出物理上合理的方式;但是,在验证范围之外使用相关性时应小心。本文基于严格评估的实验数据,提出了一种新的广泛的环戊烷粘度相关性。该相关性旨在与最近开发的状态方程一起使用,它在高达 380 MPa 的液体范围内从三相点到 360 K 和低压蒸汽范围内的 460 K 有效。所有主要数据拟合的平均绝对百分比偏差为 0.8%,偏差为 -0.3%。整个拟合的估计扩展不确定性为 2.7%(在 95% 的置信水平下),而大气压附近从 298 K 到 460 K 的不确定性增加到 4%。当外推到 500 MPa 时,相关性表现出物理上合理的方式;但是,在验证范围之外使用相关性时应小心。
更新日期:2019-12-01
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