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Hybrid nanocomposites of carboxymethyl cellulose cross-linked by in-situ formed Cu2O nanoparticles for photocatalytic applications
Journal of Organometallic Chemistry ( IF 2.3 ) Pub Date : 2020-02-24 , DOI: 10.1016/j.jorganchem.2020.121180
V.V. Spiridonov , X.Y. Liu , S.B. Zezin , I.G. Panova , A.V. Sybachin , A.A. Yaroslavov

A one-step on air synthesis of water-soluble composites from carboxymethylcellulose sodium salt (CMC) and Cu2O nanoparticles, ca. 10 nm in diameter is described. The polymer matrix stabilizes the nanoparticles against aggregation via electrostatic interaction between carboxyl groups of the polymer and Cu(1+)-ions on the nanoparticle surface. Being dispersed in water, the composites initiate a photocatalytic oxidation of an azo dye Methyl Orange. The oxidation proceeds in the presence of oxygen and accelerates significantly up to a 100 conversion when hydrogen peroxide is added. The Cu2O-CMC composites have potential for photochemical decomposition of organic contaminants in water waste.



中文翻译:

原位形成Cu 2 O纳米粒子交联的羧甲基纤维素杂化纳米复合材料光催化中的应用

从羧甲基纤维素钠盐(CMC)和Cu 2 O纳米粒子进行空气合成水溶性复合材料的一步,大约 描述了直径10nm。聚合物基质通过聚合物的羧基与纳米颗粒表面上的Cu(1+)离子之间的静电相互作用,稳定了纳米颗粒,防止聚集。分散在水中后,复合材料会引发偶氮染料甲基橙的光催化氧化。在存在氧气的情况下,氧化会发生,当添加过氧化氢时,氧化会显着加速至100转化。Cu 2 O-CMC复合材料具有光化学分解废水中有机污染物的潜力。

更新日期:2020-02-24
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