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Embedding a boroxazine ring into a nanographene scaffold by a concise bottom-up synthetic strategy.
Chemical Communications ( IF 4.9 ) Pub Date : 2020/02/24 , DOI: 10.1039/d0cc00471e
Michael Fingerle 1 , Holger F Bettinger
Affiliation  

Embedding a boroxazine (B3N2O) heterocycle by a m-quinquephenyl scaffold renders a B/N/O substituted nanographene molecule. The target compound can be synthesized in four steps and in good overall yield. The incorporation of a boroxazine core modifies the electronic structure and results in high fluorescence quantum yield.

中文翻译:

通过简洁的自下而上的合成策略将硼环嗪环嵌入纳米石墨烯支架中。

通过间喹啉苯基支架嵌入环硼嗪(B3N2O)杂环可得到B / N / O取代的纳米石墨烯分子。可以分四个步骤合成目标化合物,并且总收率良好。掺入硼环嗪核修饰了电子结构,并导致高荧光量子产率。
更新日期:2020-04-03
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