当前位置: X-MOL 学术Electrochem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Peat-derived carbon-based non-platinum group metal type catalyst for oxygen reduction and evolution reactions
Electrochemistry Communications ( IF 5.4 ) Pub Date : 2020-02-24 , DOI: 10.1016/j.elecom.2020.106700
P. Teppor , R. Jäger , M. Paalo , R. Palm , O. Volobujeva , E. Härk , Z. Kochovski , T. Romann , R. Härmas , J. Aruväli , A. Kikas , E. Lust

For the first time, a novel peat-derived carbon (PDC) was used to synthesize an active non-platinum group metal type catalyst for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The obtained catalyst exhibited a smaller specific surface area and was more graphitic compared to a catalyst synthesized identically but using carbide-derived carbon (CDC) instead of PDC. Due to the organic nature of the used peat, the PDC contained numerous additives. In 0.1 M KOH, both the PDC and CDC-based catalysts displayed ORR activity comparable to Pt/Vulcan. Additionally, equally high OER activities of 1.59 V vs RHE at 10 mA cm-2 were reached for both catalysts studied. Considering the remarkable bifunctional activity of the PDC-based catalyst, it can be concluded that PDC is an exceptionally promising carbon support material for ORR and OER catalysts.



中文翻译:

泥炭衍生的碳基非铂族金属型催化剂,用于氧还原和放出反应

首次使用新型的泥炭衍生碳(PDC)合成了用于氧还原反应(ORR)和氧释放反应(OER)的活性非铂族金属型催化剂。与相同合成但使用碳化物衍生的碳(CDC)代替PDC的催化剂相比,所获得的催化剂表现出较小的比表面积并且具有更多的石墨。由于所用泥炭的有机性质,PDC包含许多添加剂。在0.1 M KOH中,PDC和CDC基催化剂均显示出与Pt / Vulcan相当的ORR活性。此外,在10 mA cm -2时,相对于RHE的1.59 V的较高OER活性研究的两种催化剂均达到了目标。考虑到PDC基催化剂的显着双功能活性,可以得出结论,PDC是ORR和OER催化剂的极有希望的碳载体材料。

更新日期:2020-02-24
down
wechat
bug