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Front Cover: Rates of Ring Opening of Radical Cation Intermediates Govern Differences in Thermoluminescence between 1‐ and 2‐Naphthyl‐Substituted Methylenecyclopropanes (ChemPhotoChem 3/2020)
ChemPhotoChem ( IF 3.7 ) Pub Date : 2020-02-24 , DOI: 10.1002/cptc.202000020
Yasunori Matsui 1, 2 , Kazuki Shimono 1 , Kosuke Takae 1 , Hayato Namai 3 , Toshiki Sera 1 , Takuya Ogaki 1 , Eisuke Ohta 1, 2 , Kazuhiko Mizuno 1, 2 , Hiroshi Ikeda 1, 2
Affiliation  

The Front Cover illustrates the difference in the reactivity between 1‐ and 2‐naphthyl‐substituted methylenecyclopropane. The weak bond in the former substance can be broken even by a small samurai resulting in pink fluorescence, whereas the strong bond in the latter cannot be broken even by a big samurai (resulting in green phosphorescence). More information can be found in the Communication by Y. Matsui et al. on page 168 in Issue 3, 2020 (DOI: 10.1002/cptc.201900230).
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中文翻译:

封面:自由基阳离子中间体的开环速率控制了1和2-萘基取代的亚甲基环丙烷之间的热致发光差异(ChemPhotoChem 3/2020)

封面说明了1-和2-萘基取代的亚甲基环丙烷之间反应性的差异。即使是小的武士也会破坏前者物质中的弱键,导致发出粉红色荧光,而即使是大武士也不会破坏后者中的强键(导致绿色磷光)。可以在Y. Matsui等人的来文中找到更多信息。就在第3年,2020年168页(:10.1002 / cptc.201900230 DOI)。
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更新日期:2020-02-24
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