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Controllable synthesis of gossamer-like Nb 2 O 5 -RGO nanocomposite and its application to supercapacitor
Journal of Nanoparticle Research ( IF 2.5 ) Pub Date : 2020-02-22 , DOI: 10.1007/s11051-020-4779-8
Weibing Hu , Sumeng Zhang , Wen Zhang , Meng Wang , Fu Feng

The gossamer-like Nb2O5-RGO nanocomposite was synthesized through a solvothermal treatment, and the Nb2O5 nanoparticles were uniformly coated on the RGO sheets. The size of the Nb2O5 nanoparticles is about 200–700 nm. The applications of Nb2O5-RGO as supercapacitor were then explored systematically. The morphology, textural structure, and physicochemical property of Nb2O5-RGO were investigated by using SEM, TEM, XRD, FT-IR, TG, and Raman. The electrochemical performance of RGO, Nb2O5, and Nb2O5-RGO was assessed through CV and galvanostatic charge-discharge test. The experimental results show that gossamer-like Nb2O5-RGO exhibits partial faradic pseudocapacitance and good electrical double layer capacitance property. The specific capacitance value 299.23 Fg−1 of Nb2O5-RGO nanocomposite is about 2.7 and 1.7 times higher than that of Nb2O5 and RGO, retaining 87.72% of its initial capacitance after 2000 cycles under the optimized conditions, which demonstrate that more ordered binary architecture Nb2O5-RGO nanocomposite along with easy synthesis possesses faster charge-discharge kinetics and excellent supercapacitive performance.



中文翻译:

蛛丝状Nb 2 O 5 -RGO纳米复合材料的可控合成及其在超级电容器中的应用

通过溶剂热处理合成了蛛丝状的Nb 2 O 5 -RGO纳米复合材料,并将Nb 2 O 5纳米颗粒均匀地涂覆在RGO片材上。Nb 2 O 5纳米粒子的大小约为200–700 nm。然后系统地探讨了Nb 2 O 5 -RGO作为超级电容器的应用。利用SEM,TEM,XRD,FT-IR,TG和Raman对Nb 2 O 5 -RGO的形貌,组织结构和理化性质进行了研究。RGO,Nb 2 O 5和Nb 2 O的电化学性能通过CV和恒电流充放电测试评估了5- RGO。实验结果表明,类似游丝的Nb 2 O 5 -RGO具有部分法拉第伪电容和良好的双电层电容性能。Nb 2 O 5 -RGO纳米复合材料的比电容值299.23 Fg -1约为Nb 2 O 5和RGO的比电容的2.7和1.7倍,在优化条件下经过2000次循环后,其比电容值保持87.72%。那更有序的二进制体系结构Nb 2 O 5-RGO纳米复合材料易于合成,具有更快的充放电动力学和出色的超电容性能。

更新日期:2020-02-22
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