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Photoredox Catalyst Free, Visible Light‐Promoted C3−H Acylation of Quinoxalin‐2(1H)‐ones in Water
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-02-21 , DOI: 10.1002/adsc.202000116
Juan Lu 1 , Xiang‐Kui He 1 , Xiao Cheng 1 , Ai‐Jun Zhang 1 , Guo‐Yong Xu 2 , Jun Xuan 1, 3
Affiliation  

A method for the synthesis of 3‐acyl quinoxalin‐2(1H )‐ones through visible‐light promoted decarboxylative acylation of α‐oxo‐carboxylic acids with quinoxalin‐2(1H )‐ones was developed. The reaction was performed in aqueous phase and photoredox catalyst was not required to run the process.

中文翻译:

水中无光氧化还原催化剂,可见光促进喹喔啉-2(1H)-one的C3-H酰化

一种用于3-酰基喹喔啉-2(1的合成方法ħ) -酮通过可见光促进脱羧的α氧代羧酸酰化与喹喔啉-2(1 H ^) -酮被开发。反应在水相中进行,并且不需要光氧化还原催化剂来进行该过程。
更新日期:2020-02-21
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