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Matrix-Free and Highly Efficient Room-Temperature Phosphorescence Carbon Dots towards Information Encryption and Decryption.
Chemistry - An Asian Journal ( IF 4.1 ) Pub Date : 2020-03-18 , DOI: 10.1002/asia.202000063
Hetong Qi 1 , Hengqi Zhang 1 , Xuemei Wu 1 , Yuhai Tang 1 , Manping Qian 2 , Ke Wang 2 , Honglan Qi 2
Affiliation  

Designing efficient room-temperature phosphorescence (RTP) carbon dots (C-dots) without the need of an additional matrix is important for various applications. Herein, matrix-free and highly efficient C-dots with yellow-green RTP emission have been successfully synthesized towards information encryption and decryption. Phytic acid (PA) and triethylenetetramine are used as molecular precursors, and a facile microwave-assisted heating method is selected as synthesis method. The obtained C-dots exhibit a maximum phosphorescence emission at around 535 nm under an excitation wavelength of 365 nm and a long average lifetime up to 750 ms (more than 9 s to the naked eye). PA containing six phosphate groups and serving as P source plays a significant role in producing the RTP C-dots. Furthermore, potential applications of the RTP C-dots in the field of information encryption and decryption are successfully demonstrated.

中文翻译:

不含矩阵且高效的室温磷光碳点,用于信息加密和解密。

设计高效的室温磷光(RTP)碳点(C-dots)而不需要额外的基质对于各种应用很重要。在此,已经成功地合成了具有黄绿色RTP发射的无矩阵且高效的C点,用于信息加密和解密。植酸(PA)和三亚乙基四胺被用作分子前体,并且选择了一种简便的微波辅助加热方法作为合成方法。所获得的C点在365 nm的激发波长下在535 nm处显示最大的磷光发射,并且平均寿命长达750 ms(肉眼超过9 s)。包含六个磷酸基团并用作P源的PA在产生RTP C点中起着重要作用。此外,
更新日期:2020-04-22
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