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Resorcin[4]arene-based cadmium(II) coordination polymers for efficent luminescent detection of Fe3+ and Cr2O72- ions
Inorganic Chemistry Communications ( IF 3.8 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.inoche.2020.107847
Ting-Ting Guo , Ying-Ying Liu , Jin Yang , Jian-Fang Ma

Abstract Two luminescent cadmium(II) coordination polymers, [Cd2(L)(BDC)2]·3DMF·5EtOH (1) and [Cd2(L)(OH-BDC)2]·2DMF·6MeOH (2), have been solvothermally prepared with resorcin[4]arene-based ligand (L) and dicarboxylic acids (H2BDC = isophthalic acid, OH-H2BDC = 5-OH-isophthalic acid and N,N′-dimethylformamide). 1 and 2 are isostructural and feature fascinating layer structures. Remarkably, 1 and 2 showed intense luminescent properties and were used as highly efficient multiple luminescent detection for Fe3+ and Cr2O72− ions.

中文翻译:

间苯二酚 [4] 芳烃基镉 (II) 配位聚合物,用于 Fe3+ 和 Cr2O72- 离子的高效发光检测

摘要 两种发光镉(II)配位聚合物[Cd2(L)(BDC)2]·3DMF·5EtOH(1)和[Cd2(L)(OH-BDC)2]·2DMF·6MeOH(2),用间苯二酚 [4] 芳烃基配体 (L) 和二羧酸(H2BDC = 间苯二甲酸,OH-H2BDC = 5-OH-间苯二甲酸和 N,N'-二甲基甲酰胺)溶剂热制备。1 和 2 是同构的,具有迷人的层状结构。值得注意的是,1 和 2 显示出强烈的发光特性,并被用作 Fe3+ 和 Cr2O72− 离子的高效多重发光检测。
更新日期:2020-04-01
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