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Electrochemical reduction of nitrous oxide in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid electrolyte
Electrochemistry Communications ( IF 5.4 ) Pub Date : 2020-02-15 , DOI: 10.1016/j.elecom.2020.106688
Hyeonsu Kim , Seungyeon Baek , Taeho Lim , Jae Jeong Kim

An ionic liquid/organic solvent mixture was adopted as an electrolyte for the electrochemical reduction of N2O. The ionic liquid and organic solvent used for the electrolyte were 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]) and propylene carbonate (PC), respectively. The use of [BMIM][BF4] in place of aqueous solutions improves the solubility of N2O and also avoids the hydrogen evolution reaction, which is the main side reaction in an aqueous solution. The low electrical conductivity and high viscosity of [BMIM][BF4], the main disadvantages in the context of electrochemical reactions, were compensated on introducing PC. The composition of the [BMIM][BF4]/PC was optimized considering both the electrical conductivity and N2O stability in the solution. For the optimized [BMIM][BF4]/PC, a high faradaic efficiency (>90%) was achieved for N2O reduction to N2.



中文翻译:

电化学还原一丁基-3-甲基咪唑四氟硼酸盐离子液体电解质中的一氧化二氮

离子液体/有机溶剂混合物被用作用于N 2 O电化学还原的电解质。用于电解质的离子液体和有机溶剂为1-丁基-3-甲基咪唑四氟硼酸酯([BMIM] [BF 4 ])和分别是碳酸亚丙酯(PC)。代替水溶液使用[BMIM] [BF 4 ],可以提高N 2 O的溶解性,并且可以避免作为氢的主要反应的氢生成反应。引入PC可以弥补[BMIM] [BF 4 ]的低电导率和高粘度,这是电化学反应中的主要缺点。[BMIM] [BF 4的组成考虑到溶液中的电导率和N 2 O稳定性,对] / PC进行了优化。对于优化的[BMIM] [BF 4 ] / PC,实现了将N 2 O还原为N 2的高法拉第效率(> 90%)。

更新日期:2020-02-20
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